Play was suspended for almost eight hours before resuming in the afternoon and 39 players never got to the first tee.
Na, who has not won on the PGA Tour but has had seven top-10 finishes this year, took advantage of the soft conditions to shoot the lowest round of his seven-year career.
Scott Verplank, Retief Goosen and Joe Durant all shot 7-under 65. Jimmy Walker was at 6-under with four holes to play when play was halted by darkness.
Stewart Cink, who defeated 59-year-old Tom Watson to win a playoff at last week's British Open, is not competing in the event.
Na played the back nine first at the Glen Abbey Golf Club and made the turn in 2-under 34. He then birdied seven holes on the front side for a 29. His best showing to date this year has been a tie for third at the Players Championship, where he finished five shots behind winner Henrik Stenson.
Copyright 2009 by United Press International.